Apparently this is some limitation placed on Android OS since Android KitKat was released. To gain access to the SD card, I had to grant Xender extra permissions.
To do this simply launch the Xender app on your device, go to Settings >> Download Location
Click on SD Card then Select Folder
Tap on your SD card and then Select.
Your Xender’s download location will switch and you’ll automatically be granted access to the SD Card as shown below
Log into Xender on your PC/Mac and the SD card permission will be gone thereby allowing you to play with files on either the internal or SD card storage.
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